QCEXVAL: QUANTUM CHEMISTRY OF THE EXCITED STATE


COST Action P9: Radiation Damage in Biomolecular Systems. A European Network

A COST network on radiation damage is initiated in early 2004. Four working groups (WG) are currently formed:

-WG1: Electron and biomolecular interactions (Chair: D Field )
-WG2: Ions and biomolecular interactions (Chair: T Schlathölter)
-WG3: Radiation in physiological environments (Chair: K McGuigan)
-WG4: Theoretical developments for radiation damage (Chair: M. C. Bacchus)
-WG5: Track Structure in cells (Chair: H Paretzke)

Our group is integrated within the Task Group 4: Theoretical Developments for Radiation Damage.
Local coordinator: Luis Serrano-Andrés
Other group participants: Manuela Merchán
Remedios González-Luque
Mercedes Rubio
Teresa Climent
Daniel Roca Sanjuán
Juan José Serrano Pérez
Gloria Olaso González
Israel González Ramírez

Coordinator of Working Group 4: Prof. Marie-Christine Bacchus, Université de Lyon, France
Coordinator of the COST Action: Prof. Nigel Mason Open Universty, United Kingdom Webpage:
http://www.isa.au.dk/cost/ho me.html

The main objective of this COST Action is to obtain a detailed understanding of the fundamental interaction processes for different types of incident radiation that occur from the initial deposition of radiative energy to the formation of radiation damage in biological material. This will be achieved by combining the wide range of complementary experimental and theoretical expertise available within the affiliated groups. A few selected prototypical bio-molecules will be used as relatively simple model systems in order to achieve the highest level of coherence in this joint venture. The information, expertise and new theoretical insights that will be obtained will then be applied to the study of more complex systems such as composite mixed clusters containing bio-molecules or e.g. plasmid DNA. The elucidation of fundamental energy transfer and coupling mechanisms, ionisation, charge transport and reaction behaviour that will be determined in this Action will in turn be used to develop models of the track structures in irradiated media. Such models can be used to determine a more reliable quantification of human epidemiological experience when humans are subject to low radiation doses in homes (e.g. local radon levels), in the workplace, in diagnostic medicine, or in transport (as caused e.g. by natural background radiation, primary and secondary cosmic rays in airplanes) or even by mobile phone use where currently there are no reliable experimental or epidemiological data available.
Our contribution falls within goal B of the network, a joint experimental/theoretical investigation to determine the role played by excited electronic states and non-adiabatic couplings on the dynamics of biomolecules interacting with ionizing radiation. This will involve the calculation of potential energy surfaces and of the coupling between electronic states, the analysis of the coordination space and the study of quantum dynamics using wave packet propagation methods.


1st COST P9 Meeting: Lyon, 24th to 27th June, 2004.
2nd COST P9 Meeting: Postdam, 16th to 20th March, 2005.
3rd COST P9 Meeting: Gröningen, 6th to 9th June, 2006.
4th COST P9 Meeting: Dublin, 19th to 22th June, 2007.

1st COST P9 Working Group 4 Meeting: Brussels, 28th October, 2004.
2nd COST P9 Working Group 4 Meeting: Lyon, spring 2007.

COST meeting:
Symposium on Radiation Effects of Biomedical Interest
Madrid, 22snd-25th February, 2007
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