The family of acridines and xanthones represent important groups of aza-aromatic compounds of interest in different areas. Acridine was discovered to be an important agent with interest in the field of photodynamic therapy, among other applications. The change on the npi* to pipi* nature of the fluorescing state upon increasing of the solvent polarity can be successfully explained by the ab initio results. On the other hand, xanthone derivatives such as thioxanthone are nowadays under intense research because of their particular spectroscopical properties, such as the lack of a expected solvatochromic shift which puzzles spectroscopists.
Group participants:
Luis Serrano-Andrés
Manuela MerchánCooperation:
Patrice Jacques and Dominique Burget
Département de Photochemie Générale
Université Haute-Alsace, Mulhouse-Colmar, France
http://www.dpg.uha.fr/Òscar Rubio-Pons
Department of Biotechnology
Royal Institute of Technology, Stockholm, Sweden
http://www.theochem.kth.se
Publications:
- "A Theoretical Insight into the Photophysics of Acridine" Ò. Rubio-Pons, L. Serrano-Andrés, and M. Merchán, J. Phys. Chem. A, 105, 9664 (2001)
- "Experimental and Theoretical Analysis of the Spectroscopy of Thioxanthone", P. Jacques, D. Burget, Ò. Rubio- Pons, and L. Serrano-Andrés In progress (2004)