1. Calculate the total number of electrons in the valence shell of all the atoms in the molecule.
Correct. The total number of valence shell electrons is 22.
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Wrong. Check the valence shell electrons of C and H atoms in the molecules.
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Wrong. Check the valence shell electrons of C and H atoms in the molecules.
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2. Accepting that this molecule does not contain triple bonds between carbon atoms, and taking into account the H/C atoms ratio, find the number of double bonds in this molecule:
Wrong. An hydrocarbon compound without double bonds should have a formula of type
CnH2n+2. The formula for a saturated hydrocarbon compound with n=4 should be C4H10..
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Wrong. A four carbon atoms hydrocarbon should have formula C6H8.
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Correct. This compound has formula type CnH2n-2
corresponding to an unsaturated compound with two double bonds. Also would fit a compound with a triple C-C bond, but this
possibility has been excluded in the introduction.
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3. Choose the skeleton of the molecule:
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Wrong. In this skeleton a carbon atom is surrounded
by three other carbon atoms. This skeleton cannot accommodate two double bonds.
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Correct. This compound has a
linear skeleton
of carbon atoms.
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Wrong. This skeleton is not in agreement with the formula of the selected compound
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4. How many electrons are required to form all the C-H bonds?
Wrong. Six C-H bonds require more than 10 electrons.
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Correct. Six C-H bonds require
12 electrons.
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Wrong. Six C-H bonds do not require as many as 14 electrons.
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5. There are 4 electrons that have not been located. How do we locate these four electrons to complete the valence shell of all the carbon atoms?
One on each C atom. | Wrong. Such electron distribution would produce four radicals (carbon atoms with unpair
electrons) that are not stable species.
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Two on each terminal atom C1 and C4 . | Wrong In this case C2 and C3 do not complete the octeto.
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Two double bonds between C1-C2 and C3-C4 atoms. | Correct All the atoms share eight electrons and the compound has a system of
two conjugated doble bonds..
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6. ¿How can we describe the geometry around each C atom??. Geometry
The four carbon atoms have a triangular planar geometry. | Correct. C1 and C4 sare bonded to one C atom and two hydrogens. C2 and C3
are bonded to two C atoms and one hydrogen. In both cases it is a AX3 environment. Triangular planar structure.
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The four carbon atoms have a tetrahedral geometry. | Wrong. A tetrahedral geometry requires three atoms around each carbon atom.
The carbon atoms have AX3 environment.
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7. What hybridization can we assign to the C atoms?
All the C atom use sp2 orbitals | Correct. All have triangular planar geometry.
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All the C atoms use sp3 orbitals | Wrong. Triangular planar geometry is not due to sp3 orbitals.
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