1. Compute the number of electrons (NT) in the valence shell for all the atoms in the molecule.
Correct. C: 4; O: 6.
Total: 16 electrons
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Wrong. Check the valence electrons of C and O.
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Wrong. Check the valence electrons of C and O.
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2. Select the central atom :
Correct. The central atom is the less electronegative. In this case
C
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Wrong. The central atom is the less electronegative.
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3. Compute the number of electrons used in single bonds:
Wrong. Two C-O bonds require four electrons.
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Correct. There are two C-O bonds that require
4 electrons
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4. To complete the octeto in the terminal atoms are required (total electrones).
Wrong. In this case each terminal O atom will only complete
6 electrones.
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Wrong. In this case each terminal O atom will only complete
7 electrones.
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Correct. In this case each O atom will complete 8 electrons.
Total 12
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5. ¿ How many electrons needs the central atom to complete the octeto?
Wrong. The central atom shares 4 electrons with the two O atoms.
Two electrons more will only complete 6 electrons around the C atom.
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Wrong. The central atom shares 4 electrons with the two O atoms.
Three electrons more will only complete 7 electrons around the C atom.
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Correct The central atom shares 4 electrons with the two O atoms.
Four electrons more will complete the 8 electrons required around the C atom. However there are no more electrons available.
¿How to we explain this problem?
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5b. ¿How do we explain this situation?
Wrong. Carbon atoms generally complete the octeto.
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Correct. The central atom shares two additional electrons with each of the
oxygen atoms.
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6. ¿How is the shape of this molecule? Structures
Correct. This molecule is of AX2 type
and adopts a linear shape.
Linear
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Wrong his molecule is of AX2 type
and cannot adopt and angular shape.
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7. ¿How is the polarity of this molecule? Polarity, Electronegatividad
Wrong. This molecule has two polar bonds. The dipolar moments cancel each other.
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Correct This molecule has two polar bonds. The dipolar moments cancel each other.
Dipols
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8. In this molecule the central atom shares four electrons with each terminal atom. The C-O bonds are double bonds, one sigma and one pi bond. ¿What orbitals uses the C atom to form the sigma bond? orbitals
Correct. The central carbon atom forms two sigma bonds using
two "sp" orbitals . The two "sp" orbitales
look similar to one "p" but they overlap in both sides with
"p" orbitals of O atoms.
del oxígeno.
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Wrong For sigma overlap C-O two orbitals are required.
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Finally pi orbitales pi orbitals complete the orbital overlap between C and O. The combination of a sigma and a pi orbital form the C=O double bond.