Organic compounds 2

⇐ To index

 

The structure of 1,3-butadiene shows the presence of two carbon-carbon double bonds. Load structure.

Hybrid orbitals

1. Inspecting that structure we can conclude that the following carbon atoms use sp3 hybrid orbitals in their bonding to other atoms:

Wrong. A sp3 hybridization involves connections around a carbon atom. None of these atoms meet that condition because      the C = C double bond computed as one.
Wrong. A sp3 hybridization involves connections around a carbon atom. None of these atoms meet that condition because      the C = C double bond computed as one.
Right. None of the carbon atoms presents sp3 hybridization.

2. Inspecting that structure we can conclude that the following carbon atoms use sp2 hybrid orbitals in their links to other atoms:

Wrong. C1 y C4 atoms present sp2 hybridization but they are not the only ones.
Wrong. C2 y C3 atoms present sp2 hybridization but they are not the only ones.
Right. The four carbon atoms present sp2 hybridization.

3. The double bond between carbon atoms in addition to a sigma bond Csp2-Csp2 there is:

One additional C-C sigma bond
Wrong. You can not have two sigma bonds between two carbon atoms.
One π bond in addition to a σ bond.
Right. The σ portion of the bond is located in the internuclear area, while the π portion is located on top of this axis.

The π bond.. See the smaller overlap of the π lobes.

4. A single bond and a double bond are different because single bond is:

Not right. The single bond, or σ bond, is stronger than a π bond. However a single bond is weaker than a double bond that has two contributors, one σ and one π contributions.
Right. The stronger is the bond the shorter is. The single bond is weaker and longer than a double bond.