One of the challenges currently faced by emerging countries is to get their citizens to decide to use sustainable transport for their regular trips, in order to reduce the current vehicular pollution rates. The objective of this descriptive research is to examine the perceptions of Dominicans regarding the state of the country’s transport systems and road infrastructure. For this purpose, a nationwide survey procedure was performed. This cross-sectional research used the data retrieved from a sample of 1260 citizens aged over 18, proportional in gender, age, habitat, and province of the Dominican Republic. The results showed how Dominicans believe that, compared to other road features, pedestrian roads and public transport vehicles remain in a very poor condition. Further, citizens report to be more interested about the improvement of road infrastructures than in the implementation of any other set of measures performed to promote sustainable road mobility, including those related with alternative transport means. Finally, this study claims for the need of fostering educational, communicative and participative actions and measures aimed at increasing the value given to sustainable transportation, and the relevance of integrate potential structural and vehicular improvements with those related to human behavior in mobility.