Publications

 

55. Tunable crossover between one- and three-dimensional magnetic dynamics in CoII Single-Chain Magnets organized by halogen bonding.
A. Amjad, J. M. Clemente-Juan, E. Coronado, F. Luis, M. Evangelisti, G. Mínguez Espallargas andE. del Barco.
Phys. Rev. B 2016, 93, 224418.

54. Single-crystal-to-single-crystal anion exchange in a gadolinium MOF: incorporation of POMs and [AuCl4]–.
J. López-Cabrelles, G. Mínguez Espallargas and E. Coronado.
Polymers 2016, 8, 171.

53. New dinuclear copper complexes incorporating bis(imidazolyl) based ligands and bidentate-monodentate oxalate bridges. Crystal structure and magnetic properties of [Cu2(BIM)2(C2O4)2]·4H2O and [Cu2(BIK)2(C2O4)2] (BIM = bis(2- imidazolyl)methane), BIK = bis(2-imidazolyl)ketone). Exploring magnetostructural correlations.
E. Escrivà, J.-V. Folgado, G. Mínguez Espallargas, L. Soto, A. Sancho, L. Perelló and R. Ortíz
Polyhedron 2016, 112, 137–144.

52. Isostructural compartmentalized spin-crossover coordination polymers for gas confinement.
N. Calvo Galve, M. Giménez-Marqués, M. Palomino, S. Valencia, F. Rey, G. Mínguez Espallargas and E. Coronado.
Inorg. Chem. Front. 2016, 3, 808–813 (special themed collection “2015 Emerging Investigators by ICF”).

51. Insertion of a [FeII(pyimH)3]2+ (pyimH = 2-(1H-Imidazol-2-yl)pyridine spin-crossover complex inside a ferromagnetic lattice based on a chiral 3D bimetallic oxalate network.
M. López-Jordà, M. Giménez-Marqués, C. Desplanches, G. Mínguez Espallargas, M. Clemente-León and E. Coronado.
Eur. J. Inorg. Chem. 2016, 2187–2192.

50. Snapshots of a solid state transformation: coexistence of three phases trapped in one single-crystal.
G. Aromí, C. M. Beavers, J. S. Costa, G. A. Craig, G. Mínguez Espallargas, A. Orera and O. Roubeau.
Chem. Sci. 2016, 7, 2907–2915.

49. Key role of the cation in the crystallization of chiral tris(anilato)metalate magnetic anions
S. Benmansour, P. Gómez-Claramunt, C. Vallés-García, G. Mínguez Espallargas and C. J. Gómez García.
Cryst. Growth Des. 2016, 16, 518−526.

48. Solvent-free synthesis of a pillared 3D coordination polymer with magnetic ordering.
J. López-Cabrelles, M. Giménez-Marqués, G. Mínguez Espallargas and E. Coronado.
Inorg. Chem. 2015, 54, 10490−10496.

47. Layered gadolinium hydroxides for magnetic cooling.
G. Abellán, G. Mínguez Espallargas, G. Lorusso, M. Evangelisti and E. Coronado.
Chem. Commun. 2015, 51, 14207–14210.

46. Blue-luminiscent organic lead bromide perovskites: highly dispersible and photostable materials.
S. Gonzalez-Carrero, G. Mínguez Espallargas, R. E. Galian and J. Pérez-Prieto.
J. Mat. Chem. A. 2015, 3, 14039–14045.

45. Quantum Error Correction with magnetic molecules.
J. J. Baldoví, S. Cardona-Serra, J. M. Clemente-Juan, L. Escalera-Moreno, A. Gaita-Ariño and G. Mínguez Espallargas.
Europhysics Lett. 2015, 110, 33001.

44. 2D and 3D anilato-based heterometallic M(I)M(III) lattices: the missing link.
S. Benmansour, P. Gómez-Claramunt, C. Vallés-García G. Mínguez Espallargas and C. J. Gómez-García.
Inorg. Chem. 2015, 54, 5410−5418.

43.Coordination polymer flexibility leads to polymorphism and permits crystalline solid-vapour reaction: a multi-technique mechanistic study.
I. J. Vitorica-Yrezábal, S. Libri, J. R. Loader, G. Mínguez Espallargas, M. Hippler, S. P. Thompson, J. E. Warren, D. Musumeci, M. D. Ward and L. Brammer.
Chem. Eur. J. 2015, 21, 8799–8811 (selected as hot paper).

42. A rare example of nickel(II) chains based on a heteroscorpionate-like ligand with quadruple imidazolyl interactions.
C. J. Gómez-García, E. Escrivà, G. Mínguez Espallargas, J. J. Borrás-Almenar, L. Soto, A. Sancho, J. García-Lozano and C. Ramírez de Arellano.
Dalton Trans. 2014, 43, 11371–11375.

41. A SIM-MOF: three-dimensional organisation of Single-Ion Magnets with anion-exchange capabilities.
J. J. Baldoví, E. Coronado, A. Gaita-Ariño, C. Gamer, M. Giménez-Marqués and G. Mínguez Espallargas.
Chem. Eur. J. 2014, 20, 10695–10702.

40. A mixed-ligand approach for spin-crossover modulation in a linear FeII coordination polymer.
N. Calvo Galve, E. Coronado, M. Giménez-Marqués and G. Mínguez Espallargas.
Inorg. Chem. 2014, 53, 4482−4490.

39. Flexible high efficiency perovskite solar cells.
C. Roldán-Carmona, O. Malinkiewicz, A. Soriano, G. Mínguez Espallargas, A. Garcia, P. Reinecke, T. Kroyer, M. I. Dar, M. K. Nazeeruddin and H. J. Bolink.
Energy Environ. Sci. 2014, 7, 994–997.

38. Non-template synthesis of CH3NH3PbBr3 perovskite nanoparticles.
L. C. Schmidt, A. Pertegás, S. González-Carrero, O. Malinkiewicz, S. Agouram, G. Mínguez Espallargas, H. J. Bolink, R. E. Galian and J. Pérez-Prieto.
J. Am. Chem. Soc. 2014, 136, 850–853.

37. Perovskite solar cells employing organic charge-transport layers.
O. Malinkiewicz, A. Yella, Y. H. Lee, G. Mínguez Espallargas, M. Graetzel, M. K. Nazeeruddin and H. J. Bolink.
Nature Photon. 2014, 8, 128–132.

36. Structural re-arrangement in two hexanuclear CuII complexes: From a spin frustrated trigonal prism to a strongly coupled antiferromagnetic soluble ring complex with a porous tubular structure.
W. Cañon-Mancisidor, C. J. Gómez-García, G. Mínguez Espallargas, A. Vega, E. Spodine, D. Venegas-Yazigi and E. Coronado.
Chem. Sci. 2014, 5, 324−332.

35. Spin-crossover modification through selective CO2 sorption.
E. Coronado, M. Giménez-Marqués, G. Mínguez Espallargas, F. Rey and I. J. Vitórica-Yrezábal.
J. Am. Chem. Soc. 2013, 135, 15986−15989 (selected as monthly highlight by the editors of Nature Chemistry: Nature Chem. 2013, 5, 984).

34. Single-crystal EPR spectroscopy of Co(II) Single-Chain Magnets.
A. Amjad, G. Mínguez Espallargas, J. Liu, J. M. Clemente-Juan, E. Coronado, S. Hill and E. del Barco.
Polyhedron 2013, 66, 218–221.

33. A family of layered chiral porous magnets exhibiting tunable ordering temperatures.
M. Atzori, S. Benmansour, G. Mínguez Espallargas, M. Clemente-León, A. Abhervé, P. Gómez-Claramunt, E. Coronado, F. Artizzu, E. Sessini, P. Deplano, A. Serpe, M. L. Mercuri and C. J. Gómez García.
Inorg. Chem. 2013, 52, 10031–10040.

32. Dynamic magnetic MOFs.
E. Coronado and G. Mínguez Espallargas.
Chem. Soc. Rev. 2013, 42, 1525–1539.

31. Chemical transformations of a crystalline coordination polymer: a multi-stage solid-vapor reaction manifold.
I. J. Vitórica-Yrezábal, G. Mínguez Espallargas, J. Soleimannejad, A. J. Florence, A. J. Fletcher and L. Brammer.
Chem. Sci. 2013, 4, 696–708.

30. Hydrogen bonding versus p-stacking in ferromagnetic interactions. Studies on a copper triazolopyridine complex.
C. Ramírez de Arellano, E. Escrivà, C. J. Gómez-García, G. Mínguez Espallargas, R. Ballesteros and B. Abarca.
CrystEngComm 2013, 15, 1836–1839.

29. Special Issue: 40th International Conference on Coordination Chemistry.
G. Mínguez Espallargas.
Coord. Chem. Rev. 2013, 257, 2419.

28. Hybrid magnetic superconductors formed by TaS2 layers and spin crossover complexes.
E. Coronado, M. Giménez-Marqués, C. Martí-Gastaldo, G. Mínguez Espallargas, E. Navarro-Moratalla and J. Waerenborgh.
Inorg. Chem. 2013, 52, 8451–8460.

27. A novel coordination polymer with an unusual [3x2] oblique copper(II) grid: [Cu2(HBIMAM)2(C4O4)3(H2O)2]n·2nH2O [BIMAM = bis(imidazol-2-yl) methylaminomethane]. X-Ray structure and magnetic characterization.
E. Escrivá, L. Soto, J. Server-Carrió, C. J. Gómez-García, G. Mínguez Espallargas, N. Ruiz, A. Sancho, J. García-Lozano and C. Ramírez de Arellano.
Polyhedron 2013, 56, 90–95.

26. Dynamic magnetic materials based on the cationic coordination polymer [Cu(btix)2]2n+ (btix = 1,4-bis(triazol-1-ylmethyl)benzene): tuning the structural and magnetic properties through anion exchange.
E. Coronado, M. Giménez-Marqués, C. J. Gómez-García and G. Mínguez Espallargas.
Inorg. Chem. 2012, 51, 12938−12947.

25. Tuning the magneto-structural properties of non-porous coordination polymers by HCl chemisorption.
E. Coronado, M. Giménez-Marqués, G. Mínguez Espallargas and L. Brammer.
Nature Commun. 2012, 3, 828.

24. One dimensional organization of free radicals via halogen bonding.
G. Mínguez Espallargas, A. Recuenco, F. M. Romero, L. Brammer and S. Libri.
CrystEngComm 2012, 14, 6381–6383.

23. Combination of magnetic susceptibility and electron paramagnetic resonance to monitor the 1D to 2D solid-state transformation in flexible metal-organic frameworks of Co(II) and Zn(II) with 1,4-bis(triazol-1-ylmethyl)benzene.
E. Coronado, M. Giménez-Marqués and G. Mínguez Espallargas.
Inorg. Chem. 2012, 51, 4403–4410.

22. Reacciones sólido-gas en sistemas cristalinos no porosos.
G. Mínguez Espallargas.
Memorias de la Real Academia Sevillana de Ciencias, 2011, 14, 137−146.

21. Different structural destinations: comparing reactions of [CuBr2(3-Brpy)2] crystals with HBr and HCl gas.
G. Mínguez Espallargas, A. J. Florence, J. van de Streek and L. Brammer.
CrystEngComm 2011, 13, 4400–4404 (Special Issue: "Dynamic behaviour and reactivity in crystalline solids").

20. Mechanistic insights into a gas-solid reaction in molecular crystals: the role of hydrogen bonding.
G. Mínguez Espallargas, J. van de Streek, P. Fernandes, A. J. Florence, M. Brunelli, K. Shankland and L. Brammer.
Angew. Chem. Int. Ed. 2010, 49, 8892–8896.

19. Halogen bonding: from organic to inorganic chemistry.
G. Mínguez Espallargas.
Encyclopedia of Supramolecular Chemistry, ed. J. L. Atwood and J. W. Steed, Taylor & Francis, 2010, 1:1, 1–8.

18. Effects of halogen bonding in ferromagnetic chains based on Co(II) coordination polymers.
J. M. Clemente-Juan, E. Coronado, G. Mínguez Espallargas, H. Adams and L. Brammer.
CrystEngComm 2010, 12, 2339–2342 (Special Issue: "New Talents").

17. Multifunctional magnetic materials obtained by insertion of a spin crossover FeIII complex into bimetallic oxalate-based ferromagnets.
M. Clemente-León, E. Coronado, M. López-Jordà, G. Mínguez Espallargas, A. Soriano-Portillo and J. C. Waerenborgh.
Chem. Eur. J. 2010, 16, 2207–2219.

16. Supramolecular interactions and smart materials: C–XX'–M halogen bonds and gas sorption in molecular solids.
G. Mínguez Espallargas.
Ideas in Chemistry and Molecular Sciences: Advances in Nanotechnology, Materials and Devices, ed. B. Pignataro, Wiley-VCH, 2010, pp. 115–138.

15. Rational modification of the hierarchy of intermolecular interactions in molecular crystal structures.
G. Mínguez Espallargas, F. Zordan, L. Arroyo Marín, H. Adams, K. Shankland, J. van de Streek and L. Brammer.
Chem. Eur. J. 2009, 15, 7554–7568.

14. Combining metals with halogen bonds.
L. Brammer, G. Mínguez Espallargas and S. Libri.
CrystEngComm 2008, 10, 1712–1727 (Highlight: CEC 10th birthday issue).

13. Competition between coordination network and halogen bond network formation: towards halogen-bond functionalised network materials using copper-iodobenzoate units.
P. Smart, G. Mínguez Espallargas and L. Brammer.
CrystEngComm 2008, 10, 1335–1344 (front cover).

12. Non-covalent interactions under extreme conditions: high pressure and low temperature diffraction studies of the metal-organic networks (4-chloropyridinium)2[CoX4] (X = Cl, Br).
G. Mínguez Espallargas, L. Brammer, D. R. Allan, C. R. Pulham, N. Robertson and J. E. Warren.
J. Am. Chem. Soc. 2008, 130, 9058–9071.

11. Ligand substitution within non-porous crystals of a coordination polymer: elimination from and insertion into Ag−O bonds by alcohol molecules in a solid-vapor reaction.
S. Libri, M. Mahler, G. Mínguez Espallargas, D. C. N. G. Singh, J. Soleimannejad, H. Adams, M. D. Burgard, N. P. Rath, M. Brunelli and L. Brammer.
Angew. Chem. Int. Ed. 2008, 47, 1693–1697.

10. Reversible gas uptake by a non-porous crystalline solid involving multiple changes in covalent bonding.
G. Mínguez Espallargas, M. Hippler, A. J. Florence, P. Fernandes, J. van de Streek, M. Brunelli, W. I. F. David, K. Shankland and L. Brammer.
J. Am. Chem. Soc. 2007, 129, 15606–15614.

9. Ligand flexibility and framework rearrangement in a new family of porous metal-organic frameworks.
S. M. Hawxwell, G. Mínguez Espallargas, D. Bradshaw, M. J. Rosseinsky, T. J. Prior, A. J. Florence, J. van de Streek and L. Brammer.
Chem. Commun. 2007, 1532–1534 (Highlighted as hot paper by Chem. Commun.; featured in RSC Chemical Science 2007, issue 5).

8. Reversible extrusion and uptake of HCl molecules by crystalline solids involving coordination bond cleavage and formation.
G. Mínguez Espallargas, L. Brammer, J. van de Streek, K. Shankland, A. J. Florence and H. Adams.
J. Am. Chem. Soc. 2006, 128, 9584–9585 (selected as the Editor’s choice weekly highlight for Chemistry: Science 2006, 313, 411).

7. Unexpected structural homologies involving hydrogen-bonded and halogen bonded networks in halopyridinium halometallate salts.
F. Zordan, G. Mínguez Espallargas and L. Brammer.
CrystEngComm 2006, 8, 425–431.

6. Diffraction studies in crystal engineering.
G. Mínguez Espallargas and L. Brammer.
Making Crystals by Design, ed. D. Braga and F. Grepioni, Wiley, 2006, pp. 241–265.

5. Structure and bonding in organometalic compounds: diffraction methods.
G. Mínguez Espallargas and L. Brammer.
Comprehensive Organometallic Chemistry 3, Vol. 1, ed. G. Parkin, Elsevier, 2006, pp. 573–603.

4. Designing intermolecular interactions between halogenated peripheries of inorganic and organic molecules: electrostatically directed M–XX'–C halogen bonds.
G. Mínguez Espallargas, L. Brammer and P. Sherwood.
Angew. Chem. Int. Ed. 2006, 45, 435–440.

3. Complementary features of inorganic and organic halogens: application to crystal engineering.
L. Brammer, F. Zordan, G. Mínguez Espallargas, S. L. Purver, L. Arroyo Marín, H. Adams and P. Sherwood.
Trans. Am. Crystallogr. Assoc. 2004, 39, 114–122.

2. Involving metals in halogen-halogen interactions: second-sphere Lewis acid ligands for perhalometallate ions (M–XX'–C).
L. Brammer, G. Mínguez Espallargas and H. Adams.
CrystEngComm 2003, 5, 343–345.

1. Symmetrical reconversion: measuring cross-correlation rates with enhanced accuracy.
P. Pelupessy, G. Mínguez Espallargas and G. Bodenhausen.
J. Magn. Reson. 2003, 161, 258–264.