M4

CIPROM/2022/60

En este proyecto proponemos la síntesis de materiales avanzados para tres aplicaciones diferentes: (1) reacciones de conversión de energía, (2) almacenamiento de hidrógeno y (3) espintrónica y detección magnética. Para alcanzar el primer objetivo, prepararemos dos familias de materiales: (i) polioxometalatos (POMs), y (ii) heteroestructuras basadas en hidróxidos dobles laminares (LDHs) con diferentes cationes divalentes y trivalentes. Para alcanzar el segundo objetivo (almacenamiento de H₂) prepararemos adsorbentes híbridos de redes metal-orgánicos/redes covalente-orgánicos (MOF/COFs) mediante síntesis topoquímica y mediante deshidrogenación topoquímica. Para el tercer tipo de aplicaciones, prepararemos: (i) MOFs quirales para fabricar dispositivos de efectos de selectividad quiral de espín inducida (CISS) utilizando ligandos de tipo ácido dicarboxílico y (ii) MOFs basados en anilato con lantanoides y otros coligandos como oxalato para obtener MOFs con comportamiento de single molecule magnet (SMM) que puedan actuar como sensores y presentar altas temperaturas de bloqueo.

Metal-organic frameworks,MOFs,layered double hydroxides,LDHs,hydrogen evolution reaction,HER,oxygen evolution reaction,OER,CO2 photo-reduction,CO2 electro-reduction,spintronics,magnetic ordering,single-molecule magnet

Manuel Molina Muriel - Universidad Politécnica de Valencia

(mamomu@doctor.upv.es)

Departamento de Química Inorgánica

Facultad de Química (Edificio F, 3^a planta)

C/ Dr. Moliner, 50

46100 Burjassot (Valencia)

Carlos.gomez@uv.es

Teléfono: 963 544 423

Conselleria de Educación, Universidades y Empleo

Vahid Mirdarvatan; Bahram Bahramian; Aliakbar Dehno Khalaji; Tereza Vaclavu; Carlos J. Gomez-García; Samia Benmansour; Smail Triki A novel mixed azido/phenoxido bridged 1D CuII coordination polymer containing o-vanillin-based compartmental ligand: Synthesis, magnetism, phenoxazinone synthase and catalytic activity in epoxidation of alkenes. Polyhedron, 2023, 244, 116581.

Rabi Sankar Sarkar; Carlos J. Gómez-García; Michael G. B. Drew; Shouvik Chattopadhyay Slow relaxation of the magnetization in two cobalt (III)/cobalt (II) dimers. New J. Chem., 2023, 47, 16913.

Rajat Saha; Kajal Gupta; Carlos J. Gómez García Strategies to Improve Electrical Conductivity in Metal-Organic Frameworks: A Comparative Study. Crystal Growth & Design, 2024, 24, 2235-2265.

Kajal; Richa Vinayak; Carlos J. Gómez-García; Samia Benmansour; Hari Pada Nayek Quadruple bridged-carbonate supported dodecanuclear [Ni₈Ca₄] coordination cluster. New J. Chem., 2024, 48, 3239.

Naba Kr Mandal; Sudeshna Nandi; Samia Benmansour; Carlos J. Gómez-García; Krishnendu Acharya; Jnan Prakash Naskar Design, synthesis and structure of a trinuclear copper (II) complex having a Cu₃OH core with regard to aspects of antiproliferative activity and magnetic properties. New J. Chem., 2024, 48, 5782.

Sarnali Sanfui; Arya Roychowdhury; Mohammad Usman; Eugenio Garribba; Carlos J. Gómez-García; Sankar Prasad Rath Metal vs Ligand Oxidation: Coexistence of Both Metal-Centered and Ligand-Centered Oxidized Species. Inorg. Chem. 2024, 63, 5423-5431.

Anissa Hannachi; Youness El Bakri; Kandasamy Saravanan; Carlos J. Gomez-García; Hatem A. Abuelizz; Rashad Al-Salahi Wajda Smirani Metamagnetism and canted antiferromagnetic ordering in two monomeric Co II complexes with 1-(2-pyrimidyl)piperazine. Hirshfeld surface analysis and theoretical studies. RSC Adv., 2024, 14, 11557.

Biplab Biswas; Anjila I. Siddiqui; Mithun Chandra Majee; Swadhin Kumar Saha; Biswajit Mondal; Rajat Saha; Carlos J. Gómez García Heptanuclear Mixed-Valence Co₄^IIICo₃^II Molecular Wheel-A Molecular Analogue of Layered Double Hydroxides with Single-Molecule Magnet Behavior and Electrocatalytic Activity for Hydrogen Evolution Reactions. Inorg. Chem. 2024, 63, 6161-6172.

Samia Benmansour; Cristina Pintado-Zaldo; Sofía H. Casal-García; Javier Martínez-Ponce; Carlos J. Gómez-García Anilato-Based Coordination Polymers with Slow Relaxation of the Magnetization: Role of the Synthetic Method and Anilato Ligand. Chem. Eur. J. 2024, (e202400410).

Samia Benmansour; Marco Segura-Andreu; Carlos J. Gomez-García Tb and Er dimers based on an asymmetric anilato ligand with slow magnetic relaxation. Inorg. Chim. Acta, 2024, 571, 122189.

Arka Patra; Avijit Das; Abhimanyu Sarkar; Carlos J. Gómez-García; Chittaranjan Sinha Tetranuclear NiII-Mannich base complex with oxygenase, water splitting and ferromagnetic and antiferromagnetic coupling properties. Dalton Trans., 2024, 53, 13515–13528.

Sarnali Sanfui; Mohammad Usman; Arya Roychowdhury; Subhadip Pramanik; Eugenio Garribba; Carlos J. Gómez García; Peter P.-Y. Chen; Sankar Prasad Rath Bridge vs Terminal Cyano-coordination in Binuclear Cobalt Porphyrin Dimers: Interplay of Electrons between Metal and Ligand and Spin-Coupling via Bridge. Inorg. Chem. 2024, 63, 15619-15633.

Rajat Saha; Carlos J. Gómez-García Extrinsically conducting MOFs: guest-promoted enhancement of electrical conductivity, thin film fabrication and applications. Chemical Society Reviews, 2024, 53, pp. 9490 - 9559.

Beatriz Gil-Hernández; Simon Millan; Irina Gruber; Christoph Janiak; Carlos J. Gómez-García; Joaquín Sanchiz Mesoxalate-Bridged Heptanuclear Copper(II) Complexes: Structure and Magnetic Properties. Magnetochemistry, 2024, V.10, 93, 1-16.

Manuel Molina-Muriel, Yong Peng, Horatiu Szalad, Antonio Ribera, Hermenegildo García LDH-derived CoTiAl mixed oxide as catalyst for photo-assisted CO₂ hydrogenation. Journal of CO₂ Utilization, 2024, 81, 102725, 1 – 10.

Manuel Molina-Muriel, Mahesh Eledath-Changarath, Archit Dhingra, Josep Albero, Juan Francisco Sanchez-Royo, Antonio Ribera, Hermenegildo García Influence of morphology and composition of spherical layered double hydroxide particles and derived mixed oxides on photocatalytic CO₂ reduction. Journal of CO₂ Utilization, 2024, 83, 102810, 1 – 14.

Samia Benmansour, Gustavo López-Martínez, Cristina Pintado-Zaldo, Sofía H. Casal García, Javier Martínez-Ponce, Carlos J. Gómez-García (2024). Structural diversity and magnetic properties of three complete series of coordination polymers with lanthanoids and anilato ligands: Size, electronegativity and synthesis method matter. En Manuel Martínez, Montserrat Ferrer (Ed.), Advances in Inorganic Chemistry. Inorganic Chemistry in Spain, Volume 84, 21-54. Academic Press Inc.

Contribuciones a congresos

A. Hernández-Paredes; S. Benmansour; C. J. Gómez-García The role of the functional groups in the structure and properties of anilato-based Dy(III) SIMs. 2nd Workshop 'Young Researchers in Chemistry', 19-20 May 2022, Valencia, Spain, Conferència en Congrés Internacional.

C. Martínez Hernández; S. Benmansour; C. J. Gómez García Anilato-based heterometallic networks showing ferrimagnetic ordering and proton transfer. 2nd Workshop 'Young Researchers in Chemistry', 19-20 May 2022, Valencia, Spain, Poster en Congrés Internacional.

C. Pintado-Zaldo; M. Capella-Argente; S. Benmansour; C. J. Gómez-García The impact of ethylene glycol versatility on magnetic properties and structure in anilato-based Single Ion Magnets. 2nd Workshop 'Young Researchers in Chemistry', 19-20 May 2022, Valencia, Spain, Poster en Congrés Internacional.

M. Capella-Argente; M. Gómez-Benmansour; C. Pintado-Zaldo; Samia Benmansour; C. J. Gómez-García From ladder to dimer, the size matters and from paramagnetic to single-ion magnets, lanthanoids make the difference. 2nd Workshop 'Young Researchers in Chemistry', 19-20 May 2022, Valencia, Spain, Poster en Congrés Internacional.

Carlos J. Gómez-García Coordination chemistry of anilato-type ligands with transition metals and lanthanoids: from tunable Tc to SMM. II Congreso Internacional de Química del Ecuador: 'Química para la vida y la sociedad', 30 May-3 June 2022, Chimborazo, Ecuador, Conferència Convidada en Congrés Internacional.

Noelia Maldonado; Ana Latorre; Félix Zamora; Álvaro Somoza; Carlos J. Gómez-García; Agatha Bastida; Pilar Amo-Ochoa A nanostructured Cu(II) coordination polymer based on alanine as a trifunctional mimic enzyme and efficient composite in the detection of Sphingobacteria. XXXVIII REUNIÓN BIENAL DE LA SOCIEDAD ESPAÑOLA DE QUÍMICA, 27-30 June 2022, Granada Spain, Conferència en Congrés Internacional.

Carlos J. Gómez-García; Antonio Hernández-Paredes; Cristina Pintado-Zaldo; Javier Martínez-Ponce; Antonio Valero-Martínez; Miriam Gómez-Benmansour; Murta Capella- Argente; Samia Benmansour Slow relaxation of the magnetization in anilato-based coordination polymers. 8th European Conference on Molecular Magnetism, 4-7 July 2022, Rennes, France, Conferència Convidada en Congrés Internacional.

Antonio Hernández-Paredes; Samia Benmansour; María Bayona-Andrés; Gustavo López-Martínez; Carlos J. Gómez-García Reversible solvent exchange in luminescent anilato-based 2D lattices with slow relaxation of the magnetization. 8th European Conference on Molecular Magnetism, 4-7 July 2022, Rennes, France, Poster en Congrés Internacional.

Samia Benmansour; Cristina Pintado-Zaldo; Antonio Valero-Martínez; Javier Martínez- Ponce; Antonio Hernández-Paredes; Miriam Gómez-Benmansour; Carlos J. Gómez-García The influence of ethylene glycol versatility on magnetic properties and structure in anilato-based Single Ion Magnets. 8th European Conference on Molecular Magnetism, 4-7 July 2022, Rennes, France, Poster en Congrés Internacional.

Amani Hind Benahsene; Fatiha Guenifa; Raounek Rouag; Carlos J. Gómez García; Lamia Bendjeddou Synthesis, characterization, crystal structure, hirshfeld surface analysis and magnetic properties of the first dapson molecule copper coordination complex. National Seminar of Physics, Chemistry and their Applications (NSPCA'23), 6-7 March 2023, Bordj-Bou-Arreridj, Algeria, Poster en Congrés Internacional.

Carlos J. Gómez-García; Samia Benmansour; Antonio Hernández-Paredes; Cristian Martínez-Hernández; Cristina Pintado-Zaldo; Javier Martínez-Ponce; Antonio Valero-Martínez; Miriam Gómez-Benmansour Anilato-based layered ferrimagnets and single-ion magnets. 5th International Conference on Functional Molecular Materials. FUNMAT2023, 29-31 March 2023, Cracovia, Poland, Conferència Convidada en Congrés Internacional.

Amani Hind Benahsene; Fatiha Guenifa; Raounek Rouag, Carlos J. Gómez-García; Lamia Bendjeddou Synthesis, crystal structure, Hirshfeld surface analysis and magnetic properties of new copper coordination complex diaquabis(4,4'-diaminodimethylsulfone-k-N)-bis(N,N'-dimethylformamide-k-O) copper(II) dinitrate. 1er Séminaire National de Chimie Appliquée (SNCA23), Blida, Algeria, 9-10 May 2023, Poster en Congrés Internacional.

Sofía H. Casal-García; Samia Benmansour; Carlos J. Gómez-García A Dy^III Layered MOF with Field-Induced Slow Relaxation of the Magnetization. 3er Workshop for Young Researchers in Chemistry, 18-19 May 2023, Valencia, Spain, Conferència en Congrés Internacional.

Carlos J. Gómez-García; Samia Benmansour; Antonio Hernández-Paredes; Cristian Martínez-Hernández; Cristina Pintado-Zaldo; Javier Martínez-Ponce; Antonio Valero-Martínez; Miriam Gómez-Benmansour The use of anilato ligands to construct magnetic and conducting MOFs XXXIX REUNIÓN BIENAL DE LA SOCIEDAD ESPAÑOLA DE QUÍMICA, 25-29 June 2023, Zaragoza, Spain, Conferència Convidada en Congrés Internacional.

Carlos J. Gómez-García; Samia Benmansour; Antonio Hernández-Paredes; Cristian Martínez-Hernández; María Bayona-Andrés Post-synthetic tunning of the magnetic properties in layered magnets and single-ion magnets (SIM). Emerging Research on Molecule-Based Magnets: from Theory to Experiment. 2023 Pre-ICMM Symposium, Guangzhou, China, 7-9 Septiembre 2023, Conferència Convidada en Congrés Internacional.

Carlos J. Gómez-García; Samia Benmansour; Antonio Hernández-Paredes; Cristina Pintado-Zaldo; Sofía H. Casal-García From 0D to 2D and 3D anilato-based single-molecule and single-ion magnets. 18th International Conference on Molecule-Based Magnets - ICMM2023, Nanjing, China, 10-14 Septiembre 2023, Conferència en Congrés Internacional.

Carlos J. Gómez-García; Samia Benmansour; Cristian Martínez-Hernández Multifunctional molecule-based magnets with anilato ligands. Multifunctional Molecule-Based Materials. Post-ICMM 2023 Symposium, Tianjin, China,15-17 Septiembre 2023, Conferència Convidada en Congrés Internacional.

Cristina Pintado-Zaldo; Samia Benmansour; Carlos J. Gómez-García Single Ion Magnets based on anilato and ethylene glycol. 1st European School on Advanced Materials. ESAM, 15-18 Octubre 2023, Gandía, Spain, Conferència en Congrés Internacional.

Sofia H. Casal-García; Samia Benmansour; Carlos J. Gómez-García A New two-Dimensional MOF with field induced Single Ion Magnet behaviour. 1st European School on Advanced Materials. ESAM, 15-18 Octubre 2023, Gandía, Spain, Conferència en Congrés Internacional.

Carlos J. Gómez-García Conducting 2D and 3D MOFs. Measurements, mechanisms and types. 1st European School on Advanced Materials. ESAM, 15-18 Octubre 2023, Gandía, Spain, Conferència Convidada en Congrés Internacional.

Raounek Rouag; Amani Hind Benahsene; Lamia Bendjeddou; Carlos J. Gómez-García; Merazig Hocine Synthesis, characterization, crystal structure and magnetic properties of the first dapson molecule copper coordination complex. 1st International on Physica-Chemistry, Materials Science and Applied Mathematics (IPCSAM'23), 27-28 November 2023, Skikda, Algeria, Poster en Congrés Internacional.

Carlos J. Gómez-García, Samia Benmansour, Antonio Hernández-Paredes, Cristina Pintado-Zaldo, Sofía H. Casal-García, Javier Martínez-Ponce Magnetic and Conducting 2D and 3D Metal Organic Frameworks. International Conference on Natural Sciences and Engineering for Sustainable Development (NSESD2024), 6-7 Marzo 2024, Asansol, West Bengal, India, invited conference.

Cristina Pintado-Zaldo, Louise Bureller, Javier Martínez-Ponce, Sofía H. Casal-García, Carlos J. Gómez-García, Samia Benmansour The first tris(anilato)metalate complex with a divalent cation and the first trimer with an anilato ligand. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.52, Conferència en Congrés Internacional. 

 Carlos J. Gómez-García, Cristina Pintado-Zaldo, Javier Martínez-Ponce, Sofía H. CasalGarcía, Samia Benmansour Slow magnetic relaxation in layered lanthanoid-anilato lattices. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.132, Conferència en Congrés Internacional.

 Sofía H. Casal-García, Gonzalo de Joz Latorre, Cristina Pintado-Zaldo, Javier MartínezPonce, Carlos J. Gómez-García, Samia Benmansour Transition metal-based magnetic heteroleptic chains with anilato and imidazole-type ligands. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.150, Poster en Congrés Internacional.

 Cristina Pintado-Zaldo, Louise Bureller, Javier Martínez-Ponce, Sofía H. Casal-García, Carlos J. Gómez-García, Samia Benmansour The first tris(anilato)metalate complex with a divalent cation and the first trimer with an anilato ligand. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.162, Poster en Congrés Internacional.

 Samia Benmansour, Javier Martínez-Ponce, Marco Segura-Andreu, Cristina Pintado-Zaldo, Sofía H. Casal-García, Carlos J. Gómez-García Slow relaxation of the magnetization in lanthanoid dimers with an asymmetric anilato ligand. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.186, Poster en Congrés Internacional.

 Samia Benmansour, Carlos J. Gómez García, Antonio Hernandez Paredes Reversible solvents exchange in layered MOFs with slow relaxation of the magnetization. 3rd Asian Conference on Molecular Magnetism, 1 – 4 September 2024, Busan, Republic of Korea, Conferència en Congrés Internacional.

 Carlos J. Gómez García, Samia Benmansour, Cristian Martínez-Hernández Ferrimagnetic order in layered anilato-based heterometallic lattices. 3rd Asian Conference on Molecular Magnetism, 1 – 4 September 2024, Busan, Republic of Korea, Conferència Convidada en Congrés Internacional.

Tesis doctorales, tesis de master y trabajos de fin de grado

Carmen Llopis Borrego Síntesis de redes extendidas de lantanoides y ligandos anilato en medio acuoso. Facultad de Química, Universidad de Valencia, Valencia, 2022, Trabajo de fin de grado.

Marco Segura Andreu Síntesis y caracterización de redes magnéticas porosas con lantanoides y ligandos de tipo anilato asimétricos. Facultad de Química, Universidad de Valencia, Valencia, 2022, Trabajo fin de grado.

Cristina Pintado Zaldo Síntesis y caracterización de redes metal-orgánicas (MOF) con propiedades de imanes mono-moleculares (SMM). Facultad de Química, Universidad de Valencia, Valencia, 2022, Tesis de master.

Celso Iniesta Martín Desarrollo de nuevas estrategias para la idenficación y cuantificación de escopolamina en bebidas alcohólicas y no alcohólicas. Facultad de Química, Universidad de Valencia, Valencia, 2023, Trabajo fin de grado.

Cristian Martínez Hernández Sensores magnéticos basados en polímeros de coordinación porosos con ordenamiento magnético. Facultad de Química, Universidad de Valencia, Valencia, 2023, Tesis doctoral.

Antonio Hernández Paredes Redes metal-orgánicas magnéticas con relajación lenta de la magnetización basadas en ligandos anilatos. Facultad de Química, Universidad de Valencia, Valencia, 2024, Tesis doctoral.