Research Group on Supramolecular Chemistry

Description

The Supramolecular Chemistry group focuses its research work on the synthesis and characterisation of polynitrogen compounds, as well as on the study of their interaction with metal ions, anions and neutral species. Special attention is dedicated to the study of systems of environmental and/or biological interest. In particular, to the development of molecules and/or complexes with antioxidant and/or anti-inflammatory, antiparasitic and/or antitumour activity. In order to prepare more efficient systems, the implementation of molecules on different solid surfaces such as nanoparticles, mesoporous solids, etc. is studied. These systems are applied to the detection of compounds of environmental interest and the development of new types of drugs. Finally, new compounds for nuclear magnetic resonance imaging are prepared and studied.

Goals CT

Development of compounds with antioxidant, antiparasitic and antitumour activity.
Detection and restructuring of compounds with environmental interest.

Research lines

Enzyme mimics
To develop different compounds or families of compounds whose purpose is the mimicry of enzymatic active centres.
Anion recognition
Development and synthesis of compounds capable of recognising anions of biological and/or environmental interest.
Synthesis of polyamides
To synthesise different families of Polyamine/Polyamide compounds by new or already established synthetic routes for the development of the different lines of research.
Contrast agents
Development of new compounds capable of acting as contrast agents in biomedicine.
Modification of solid surfaces
Development of oxide nanoparticles and their functionalisation with different receptors for catalysis, pharmacological application.
Biomimetic chemistry of copper. Application to NMR
Study of biomimetic compounds and copper enzymes by paramagnetic NMR.

Results

Management

GARCIA-ESPAÑA MONSONIS, ENRIQUE
PDI-Emerit/a Universitat

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Members

JIMENEZ GARCIA, HERMAS RAFAEL
PDI-Titular d'Universitat

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LLINARES BERENGUER, JOSE MIGUEL
PDI-Titular d'Universitat

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VERDEJO VIU, BEGOÑA
Alumn.-Servei de Formacio Permanent

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Non-UV research staff

Collaborators

María Desamparados Soriano Soto - Universitat Politècnica de València

Scientific production by UV researcher

JIMENEZ GARCIA, HERMAS RAFAEL
PDI-Titular d'Universitat
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- H.R. Jiménez, M. Julve, J.M. Moratal y J. Faus.(1987)Stability Constants of Metalloporphyrins. A Study of the Protonation, Deprotonation, and Formation of Copper(II) and Zinc(II) Complexes of meso-Tetra(p-sulphonatophenyl) porphyrin.Chemical Communications, pp. 910 - 911. ISSN: 1359-7345
- H.R. Jiménez, M. Julve, J.M. Moratal y J. Faus.(1987)High-Spin Iron(III) porphyrins with unusual Electron-Spin-Resonance Spectra. Synthesis and characterization of some derivatives of FeIIITPPS.Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands Chemical Society, 106(6-7), pp. 327 - 327. ISSN: 0165-0513
- H.R. Jiménez, M. Julve, J.M. Moratal y J. Faus.(1987)Protonation, deprotonation and formation of copper(II) and zinc(II) complexes of Mesotetra(parasulphonatephenyl)porphyrin.Recueil des Travaux Chimiques des Pays-Bas-Journal of the Royal Netherlands Chemical Society, 106(6-7), pp. 335 - 335. ISSN: 0165-0513
- H.R. Jiménez, J.M. Moratal, J. Faus y M. Momenteau.(1990)Acid-Base Equilibria of Iron(III) Basket-Handle Porphyrins. Formation of novel Anionic Dihydroxo Complexes.New Journal of Chemistry, 14, pp. 13 - 18. ISSN: 1144-0546
- H.R. Jiménez, M. Julve y J. Faus.(1991)A Solution Study of the Protonation and Deprotonation Equilibria of 5,10,15,20-Tetra(p-sulphonatophenyl)porphyrin. Stability Constants of its Magnesium(II), Copper(II) and Zinc(II) Complexes.Journal of the Chemical Society-Dalton Transactions, pp. 1945 - 1949. ISSN: 1472-7773
- H.R. Jiménez, M. Julve y J. Faus.(1991)Síntesis y Caracterización de algunos Derivados de la Metaloporfirina Mesotetra(parasulfonatofenil)porfirinatoferrato(III), FeTPPS3-.Anales de Quimica, 87, pp. 726 - 729. ISSN: 1130-2283
- J.M. Moratal, M.J. Martinez, A. Donaire, J. Castells, J. Salgado y H.R. Jiménez.(1991)Spectroscopic Studies of Nickel(II) Carbonic Anhydrase and its Adducts with Inorganic Anions.Journal of the Chemical Society-Dalton Transactions, pp. 3393 - 3399. ISSN: 1472-7773
- J.M. Moratal, A. Donaire, J. Castells, H.R. Jiménez, J. Salgado y F. Hillerns.(1992)Spectroscopic Studies of the Interaction of Nickel(II) Carboxypeptidase with Phosphate and Pyrophosphate.Journal of the Chemical Society-Dalton Transactions, pp. 713 - 717. ISSN: 1472-7773
- J.M. Moratal, M.J. Martinez-Ferrer, H.R. Jiménez, A. Donaire, J. Castells y J. Salgado.(1992)1H NMR and UV-Vis Spectroscopic Characterization of Sulfonamide Complexes of Nickel(II)-Carbonic Anhydrase. Resonance Assignments based on NOE Effects.Journal of Inorganic Biochemistry, 45, pp. 231 - 243. ISSN: 0162-0134
- J.M. Moratal, J. Castells, A. Donaire, J. Salgado y H.R. Jiménez.(1992)Interaction of carboxylate inhibitors with the active site of Nickel(II) Carboxypeptidase A.Journal of the Chemical Society-Dalton Transactions, pp. 3317 - 3324. ISSN: 1472-7773
- J.M. Moratal, J. Salgado, A. Donaire, H.R. Jiménez y J. Castells.(1993)1D and 2D-NMR Studies of the pH Effects on the Metal-site Geometry in Nickel(II)-Azurin from Pseudomonas aeruginosa.Chemical Communications, pp. 110 - 112. ISSN: 1359-7345
- J.M. Moratal, A. Donaire, J. Salgado, H.R. Jiménez, J. Castells y M. Piccioli.(1993)Two Dimensional 1H-NMR Spectra of Ferricytochrome C551 from Pseudomonas aeruginosa.Febs Letters, 324, pp. 305 - 308. ISSN: 0014-5793
- J.M. Moratal, J. Salgado, A. Donaire, H.R. Jiménez y J. Castells.(1993)COSY and NOESY Characterization of Co(II)-Substituted Azurin from Pseudomonas aeruginosa.Inorganic Chemistry, 32, pp. 3587 - 3588. ISSN: 0020-1669
- J.M. Moratal, J. Salgado, A. Donaire, H.R. Jiménez, J. Castells y M.J. Martinez-Ferrer.(1993)1H 2D-NMR Characterization of Ni(II)-Substituted Azurin from Pseudomonas aeruginosa.Magnetic Resonance in Chemistry, 31, pp. S41 - S46. ISSN: 0749-1581
- J.M. Moratal, J. Castells, A. Donaire, J. Salgado, H.R. Jiménez y R. Domingo.(1994)Interaction of Cobalt Ions with Carboxypeptidase A.Journal of Inorganic Biochemistry, 53, pp. 1 - 11. ISSN: 0162-0134
- H.R. Jiménez y M. Momenteau.(1994)Synthesis and Characterization of Water Soluble Superstructured Porphyrins and their Iron Complexes.New Journal of Chemistry, 18, pp. 569 - 574. ISSN: 1144-0546
- H.R. Jiménez, J.M. Moratal, J. Faus y M. Momenteau.(1994)A Solution Study of the Interaction of Superstructured Iron(III) Porphyrins with Catechol.New Journal of Chemistry, 18, pp. 1247 - 1252. ISSN: 1144-0546
- J.M. Moratal, A. Romero, J. Salgado, A. Perales-Alarcón y H.R. Jiménez.(1995)The Crystal Structure of Nickel(II)-Azurin.European Journal of Biochemistry, 228, pp. 653 - 657. ISSN: 0014-2956
- J. Salgado, H.R. Jiménez, A. Donaire y J.M. Moratal.(1995)1H NMR Study of a Cobalt-Substituted Blue Copper Protein: Pseudomonas aeruginosa Co(II)-azurin.European Journal of Biochemistry, 231, pp. 358 - 369. ISSN: 0014-2956
- H.R. Jiménez y M. Momenteau.(1996)Synthesis and Characterization of Superstructured Rhodium Porphyrins.Inorganica Chimica Acta, 244(2), pp. 171 - 177. ISSN: 0020-1693
- J. Salgado, H.R. Jiménez, J.M. Moratal, S. Kroes, G.C.M. Warmerdam y G.W. Canters.(1996)Paramagnetic Cobalt and Nickel Derivatives of Alcaligenes denitrificans Azurin and Its M121Q Mutant. A 1H NMR Study.Biochemistry, 35, pp. 1810 - 1819. ISSN: 0006-2960
- H.R. Jiménez, J. Salgado, J.M. Moratal y I. Morgenstern-Badarau(1996)EPR and Magnetic Susceptibility Studies of Cobalt(II) and Nickel(II) Substituted Azurins from Pseudomonas aeruginosa. Electronic Structure of the Active Sites.Inorganic Chemistry, 35, pp. 2737 - 2741. ISSN: 0020-1669
- H.R. Jiménez, J.M. Moratal, J. Latorre y M. Momenteau.(1997)Studies of Water Soluble Paramagnetic Iron(III) Porphyrins.New Journal of Chemistry, 21, pp. 223 - 230. ISSN: 1144-0546
- A. Donaire, H.R. Jiménez, J.M. Moratal, M.A. De la Rosa, M. Hervás, J.A. Navarro, D. Monleón, R. Tejero y B. Celda.(1998)Homology Predicted Structure and Comparison with Secondary Structure from NMR Data for Plastocyanin from the Cyanobacterium Synechocystis sp. PCC 6803.Inorganica Chimica Acta, 275-276, pp. 73 - 89. ISSN: 0020-1693
- N. Duran, W. Clegg, L. Cucurull-Sánchez, R. A. Coxall, H.R. Jiménez, J.M. Moratal, F. Lloret y P. González-Duarte.(2000)Research Group on Supramolecular ChemistryInorganic Chemistry, 39, pp. 4821 - 4832. ISSN: 0020-1669
- H.R. Jiménez, J.M. Moratal y B. Loock.(2002)Research Group on Supramolecular ChemistryNew Journal of Chemistry, 26, pp. 323 - 329. ISSN: 1144-0546
- D. Monleón, F. Ribes, H.R. Jiménez, J.M. Moratal y B. Celda.(2004)Research Group on Supramolecular ChemistryInorganica Chimica Acta, 357(4), pp. 1111 - 1118. ISSN: 0020-1693
- C. Miranda, F. Escartí, L. Lamarque, E. García-España, P. Navarro, J. Latorre, F. Lloret, H.R. Jiménez y M.J.R. Yunta.(2005)Research Group on Supramolecular ChemistryEuropean Journal of Inorganic Chemistry, 2005, pp. 189 - 208. ISSN: 1434-1948
- H.R. Jiménez, E. Ruiz de Sola, J.M. Moratal y M. Arbona.(2005)Research Group on Supramolecular ChemistryZeitschrift für Anorganische und Allgemeine Chemie, 631, pp. 2020 - 2025. ISSN: 0044-2313
- B. Verdejo, J. Aguilar, A. Doménech, C. Miranda, P. Navarro, H.R. Jiménez, C. Soriano y E. García-España.(2005)Research Group on Supramolecular ChemistryChemical Communications, 2005, pp. 3086 - 3088. ISSN: 1359-7345
- H.R. Jiménez, C. Pardal y J.M. Moratal.(2005)Research Group on Supramolecular ChemistryPolyhedron, 24(14), pp. 1813 - 1820. ISSN: 0277-5387
- M.T. Albelda, E. García-España, H.R. Jiménez, J.M. Llinares, C. Soriano, A. Sornosa-Ten y B. Verdejo.(2006)Research Group on Supramolecular ChemistryDalton Transactions, 2006, pp. 4474 - 4481. ISSN: 1477-9226
- B. Verdejo, S. Blasco, E. García-España, F. Lloret, P. Gaviña, C. Soriano, S. Tatay, H. R. Jiménez, A. Doménech, J. Latorre.(2007)Research Group on Supramolecular ChemistryDalton Transactions, 2007, pp. 4726 - 4737. ISSN: 1477-9226
- B. Verdejo, S. Blasco, J. González, E. García-España, P. Gaviña, S. Tatay, A. Doménech, M. T. Doménech-Carbó, H. R. Jiménez, C. Soriano.(2008)Research Group on Supramolecular ChemistryEuropean Journal of Inorganic Chemistry, 2008, pp. 84 - 97. ISSN: 1434-1948
- A. González-Alvarez, I. Alfonso, J. Cano, P. Díaz, V. Gotor, V. Gotor-Fernández, E. García-España, S. García-Granda, H. R. Jiménez, F. Lloret.(2009)Research Group on Supramolecular ChemistryAngewandte Chemie, 48, pp. 6055 - 6058. ISSN: 1433-7851
- E. Delgado-Pinar, N. Montoya, M. Galiana, M. T. Albelda, J. C. Frias, H. R. Jiménez, E. Garcia-España, J. Alarcón.(2010)Research Group on Supramolecular ChemistryNew Journal of Chemistry, 34, pp. 567 - 570. ISSN: 1144-0546
- C. E. Castillo, M. A. Máñez, J. González, J. M. Llinares, H. R. Jiménez, M. G. Basallote, E. García-España.(2010)Research Group on Supramolecular ChemistryChemical Communications, 46, pp. 6081 - 6083. ISSN: 1359-7345
- E. Delgado-Pinar, C. Rotger, A. Costa, M. N. Piña, H. R. Jiménez, J. Alarcón, E. García-España.(2012)Research Group on Supramolecular ChemistryChemical Communications, 48, pp. 2609 - 2611. ISSN: 1359-7345
- S. Blasco, J. Cano, M. P. Clares, S. García-Granda, A. Doménech, H. R. Jiménez, B. Verdejo, F. Lloret, E. García-España.(2012)Research Group on Supramolecular ChemistryInorganic Chemistry, 51, pp. 11698 - 11706. ISSN: 0020-1669
- C. E. Castillo, J. González-García, J. M. Llinares, M. A. Máñez, H. R. Jiménez, E. García-España y M. G. Basallote(2013)Research Group on Supramolecular ChemistryDalton Transactions, 42, pp. 6131 - 6141. ISSN: 1477-9226
- R. Belda, S. Blasco, B. Verdejo, H. R. Jiménez, A. Doménech-Carbó, C. Soriano, J. Latorre, C. Terencio y E. García-España(2013)Research Group on Supramolecular ChemistryDalton Transactions, 42, pp. 11194 - 11204. ISSN: 1477-9226
- J. González-García, A. Martínez-Camarena, B. Verdejo, M. P. Clares, C. Soriano, E. García-España, H. R. Jiménez, A. Doménech-Carbó, R. Tejero, E. Calvo, L. Briansó-Llort, C. Serena, S. Trefler, A. García-España.(2016)Research Group on Supramolecular ChemistryJournal of Inorganic Biochemistry, 163, pp. 230 - 239. ISSN: 0162-0134
- M. P. Clares, L. Acosta-Rueda, C. E. Castillo, S. Blasco, H. R. Jiménez, E. García-España y M. G. Basallote(2017)Research Group on Supramolecular ChemistryInorganic Chemistry, 56, pp. 4400 - 4412. ISSN: 0020-1669
- H. R. Jiménez, M. Arbona(2018)Research Group on Supramolecular ChemistryJournal of Coordination Chemistry, 71, pp. 890 - 905. ISSN: 0095-8972
- A. Lopera; A. Gil-Martínez; J. Pitarch-Jarque; B. Verdejo; S. Blasco; M. P. Clares; H. R. Jiménez; E. García-España(2020)Research Group on Supramolecular ChemistryDalton Transactions, 49, pp. 8614 - 8624. ISSN: 1477-9226
- J. Pitarch-Jarque, H. R. Jiménez, E. Kalenius, S. Blasco, A. Lopera, M. P. Clares, K. Rissanen, E. García-España(2021)Research Group on Supramolecular ChemistryDalton Transactions, 50, pp. 9010 - 9015. ISSN: 1477-9226
- I. Bonastre-Sabater, A. Lopera, A. Martínez-Camarena, S, Blasco, A. Doménech-Carbó, H. R. Jiménez, B. Verdejo, E. García-España, M. P. Clares(2024)Research Group on Supramolecular ChemistryDalton Transactions, 53, pp. 16480 - 16494. ISSN: 1477-9226

CNAE

Other research and experimental development on natural sciences and engineering

Associated structure

Institute of Molecular Science

www.uv.es/icmol

iu.ciencia.molecular@uv.es

Contact group details

Supramolecular Chemistry (SUPRAMOL)

Burjassot/Paterna Campus

Science Park
C/ Catedrático José Beltrán, 2

46980 Paterna (Valencia)

+34 963 544 879

Geolocation

www.uv.es/supramol

alvaro.martinez@uv.es

Contact people

GARCIA-ESPAÑA MONSONIS, ENRIQUE
PDI-Emerit/a Universitat

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Research Group on Supramolecular Chemistry - SUPRAMOL