MM2DAE

PID2021-125907NB-I00

This project raises four general objectives, all of them based on 2D materials with layered double hydroxides (LDHs) and metal-organic networks (MOFs) for possible energy and environmental applications.

The first objective is the design and synthesis of LDHs and compounds with LDH and graphene derivatives, for their use as catalysts for energy conversion reactions such as hydrogen (HER) and oxygen (OER) evolution reactions or photo- or electrocatalytic CO₂ reduction into other carbon-containing compounds of interest and fuels such as CO, CH₄, CH₃OH, etc.

The second objective is the synthesis of two-dimensional MOFs with redox-active anilato-type ligands, that can be easily reduced. The electrocatalytic activity of these 2D MOFs will be measured for the hydrogen and oxygen evolution reactions.

The third objective focuses on spintronics, since it is intended to prepare 2D MOFs with electrical conductivity and magnetic ordering. For this aim, we will use anilato-type bridging ligands since they can be easily reduced and functionalized to modulate their electronic properties. We will use different transition metals to ensure magnetic ordering. Later these 2D MOFs will be delaminated in thin films with the final objective of preparing a spin valve device.

The last objective is the synthesis of 2D and 3D MOFs with anilato-type ligands and transition metals or lanthanoids with magnetic ordering or with single-molecule magnet (SMM) behavior. These MOFs will be used in solvent exchange reactions and their ability to absorb different solvents, gases, toxic metal ions and polluting organic molecules will be measured. The ultimate goal is to obtain systems that can remove various pollutants from water. The change in the magnetic properties of these MOFs could make them useful as magnetic chemical sensors. Finally, the luminescent properties of the lanthanoid-containing MOFs will be measured in order to prepare optical sensors based on these MOFs.

Metal-organic frameworks,MOFs,layered double hydroxides,LDHs,hydrogen evolution reaction,HER,oxygen evolution reaction,OER,CO2 photo-reduction,CO2 electro-reduction,spintronics,magnetic ordering,electrical conductivity,single-molecule magnet

Manuel Molina Muriel - Polytechnic University of Valencia

mamomu@doctor.upv.es

Department of Inorganic Chemistry

Faculty of Chemistry (Building F, 3rd floor)

C/ Dr. Moliner, 50

46100 Burjassot (Valencia)

Carlos.gomez@uv.es

Teléfono: 963 544 423

PID2021-125907NB-I00 project supported by:

Arijit Sarkar; Debayan Basu; Carlos J. Gómez-García; Hari Pada Nayek Field-Induced SMM Behaviour of Tetranuclear Coordination Clusters with a Cubane [Ni₄O₄] Core. European Journal of Inorganic Chemistry, 2022 (e202200565), pp. 1 - 7. 

Patrick J. Desrochers; Ali Abdulrahim; Katherine R. Demaree; Joseph A. Fortner; Jamie D. Freeman; Makenzie Provorse Long; Madison E. Martin; Carlos J. Gómez-García; Nikolay Gerasimchuk Rational Design of Iron Spin-Crossover Complexes Using Heteroscorpionate Chelates. Inorganic Chemistry, 2022, 61, pp. 18907 - 18922. 

Samia Benmansour; Cristina Pintado-Zaldo; Javier Martínez-Ponce; Antonio Hernández-Paredes; Antonio Valero-Martínez; Miriam Gómez-Benmansour; Carlos J. Gómez-García The versatility of ethylene glycol to tune the dimensionality and magnetic properties in DyIII-anilato-based single-ion magnets. Crystal Growth & Design, 2023, 1269 - 1280.

Soumen Kumar Dubey; Maxcimilan Patra; Kajal Gupta; Subham Bhattacharjee; Rajat Saha; Carlos J. Gómez-García A 3D Coordination Polymer Based on Syn-Anti Bridged [Mn(RCOO)₂]_n Chains Showing Spin-Canting with High Coercivity and an Ordering Temperature of 14 K. Magnetochemistry, 2023, 9, 55.

Mengle Yang; Xinming Wang; Carlos J. Gómez-García; Zhongxin Jin; Jianjiao Xin; Xixian Cao; Huiyuan Ma; Haijun Pang; Lichao Tan; Guixin Yang; Yuhe Kan Efficient Electron Transfer from an Electron-Reservoir Polyoxometalate to Dual-Metal-Site Metal-Organic Frameworks for Highly Efficient Electroreduction of Nitrogen. Advanced Functional Materials, 2023 (2214495), pp. 1 - 13.

Richa; Akhilesh Kumar; Indresh Verma; Pankaj Garg; Rohan D. Erande; Saleem Javed; Amit Rajput; Carlos J. Gomez Garcia; Antonio J. Mota; Himanshu Arora Magnetic properties and pH-controlled reversible interconversion of μ-oxido into μ-hydroxido in oxo-carboxylato bridged iron (III) dimers: Theoretical and experimental insights. Journal of Molecular Structure, 2023, 1285, 135426.

Benmansour, S.; Hernández-Paredes, A.; Defez-Aznar, K.; Gómez-García, C.J. Two-Dimensional Lattices with Lanthanoids, Anilato Ligands and Formamide. Crystals 2023, 13, 939.

Walter Cañón-Mancisidor; Patricio Hermosilla-Ibáñez; Evgenia Spodine; Verónica Paredes-García; Carlos J. Gómez-García; Diego Venegas-Yazigi Spin Frustrated Pyrazolato Triangular CuII Complex: Structure and Magnetic Properties, an Overview. Magnetochemistry, 2023, 9, 155.

Vahid Mirdarvatan; Bahram Bahramian; Aliakbar Dehno Khalaji; Tereza Vaclavu; Carlos J. Gomez-García; Samia Benmansour; Smail Triki A novel mixed azido/phenoxido bridged 1D CuII coordination polymer containing o-vanillin-based compartmental ligand: Synthesis, magnetism, phenoxazinone synthase and catalytic activity in epoxidation of alkenes. Polyhedron, 2023, 244, 116581.

Rabi Sankar Sarkar; Carlos J. Gómez-García; Michael G. B. Drew; Shouvik Chattopadhyay Slow relaxation of the magnetization in two cobalt (III)/cobalt (II) dimers. New J. Chem., 2023, 47, 16913.

Ryotaro Moriyasu; Sergio Moles Quintero; Carlos J. Gómez-García; Kazumasa Suzuki; Chitoshi Kitamura; Michihisa Murata; Mercedes Alonso; Juan Casado; Shin-ichiro Kato Isomerism Tunes the Diradical Character of DifluorenoPyrroles at constant Hückel-level Antiaromaticity. Chemical Science, 2023, 14, pp. 13468 - 13474.

Rajat Saha; Kajal Gupta; Carlos J. Gómez García Strategies to Improve Electrical Conductivity in Metal-Organic Frameworks: A Comparative Study. Crystal Growth & Design, 2024, 24, 2235-2265.

Kajal; Richa Vinayak; Carlos J. Gómez-Garciá; Samia Benmansour; Hari Pada Nayek Quadruple bridged-carbonate supported dodecanuclear [Ni₈Ca₄] coordination cluster. New J. Chem., 2024, 48, 3239.

Naba Kr Mandal; Sudeshna Nandi; Samia Benmansour; Carlos J. Gómez-García; Krishnendu Acharya; Jnan Prakash Naskar Design, synthesis and structure of a trinuclear copper (II) complex having a Cu₃OH core with regard to aspects of antiproliferative activity and magnetic properties. New J. Chem., 2024, 48, 5782.

Sarnali Sanfui; Arya Roychowdhury; Mohammad Usman; Eugenio Garribba; Carlos J. Gómez-García; Sankar Prasad Rath Metal vs Ligand Oxidation: Coexistence of Both Metal-Centered and Ligand-Centered Oxidized Species. Inorg. Chem., 2024, 63, 5423-5431.

Anissa Hannachi; Youness El Bakri; Kandasamy Saravanan; Carlos J. Gomez-García; Hatem A. Abuelizz; Rashad Al-Salahi Wajda Smirani Metamagnetism and canted antiferromagnetic ordering in two monomeric Co II complexes with 1-(2-pyrimidyl)piperazine. Hirshfeld surface analysis and theoretical studies. RSC Adv., 2024, 14, 11557.

Biplab Biswas; Anjila I. Siddiqui; Mithun Chandra Majee; Swadhin Kumar Saha; Biswajit Mondal; Rajat Saha; Carlos J. Gómez García Heptanuclear Mixed-Valence Co₄^IIICo₃^II Molecular Wheel-A Molecular Analogue of Layered Double Hydroxides with SingleMolecule Magnet Behavior and Electrocatalytic Activity for Hydrogen Evolution Reactions. Inorg. Chem., 2024, 63, 6161-6172.

Samia Benmansour; Cristina Pintado-Zaldo; Sofía H. Casal-García; Javier Martínez-Ponce; Carlos J. Gómez-García Anilato-Based Coordination Polymers with Slow Relaxation of the Magnetization: Role of the Synthetic Method and Anilato Ligand. Chem. Eur. J., 2024, e202400410.

Samia Benmansour; Marco Segura-Andreu; Carlos J. Gomez-García Tb and Er dimers based on an asymmetric anilato ligand with slow magnetic relaxation. Inorg. Chim. Acta, 2024, 571, 122189.

Arka Patra; Avijit Das; Abhimanyu Sarkar; Carlos J. Gómez-García; Chittaranjan Sinha Tetranuclear NiII-Mannich base complex with oxygenase, water splitting and ferromagnetic and antiferromagnetic coupling properties. Dalton Trans., 2024, 53, 13515–13528.

Sarnali Sanfui; Mohammad Usman; Arya Roychowdhury; Subhadip Pramanik; Eugenio Garribba; Carlos J. Gómez García; Peter P.-Y. Chen; Sankar Prasad Rath Bridge vs Terminal Cyano-coordination in Binuclear Cobalt Porphyrin Dimers: Interplay of Electrons between Metal and Ligand and Spin-Coupling via Bridge. Inorg. Chem. 2024, 63, 15619-15633.

Rajat Saha; Carlos J. Gómez-García Extrinsically conducting MOFs: guest-promoted enhancement of electrical conductivity, thin film fabrication and applications. Chemical Society Reviews, 2024, 53, pp. 9490 - 9559.

Conference Contributions

A. Hernández-Paredes; S. Benmansour; C. J. Gómez-García The role of the functional groups in the structure and properties of anilato-based Dy(III) SIMs. 2nd Workshop 'Young Researchers in Chemistry', 19-20 May 2022, Valencia, Spain, Conference in International Congress.

C. Martínez Hernández; S. Benmansour; C. J. Gómez García Anilato-based heterometallic networks showing ferrimagnetic ordering and proton transfer. 2nd Workshop 'Young Researchers in Chemistry', 19-20 May 2022, Valencia, Spain, Poster at International Congress.

C. Pintado-Zaldo; M. Capella-Argente; S. Benmansour; C. J. Gómez-García The impact of ethylene glycol versatility on magnetic properties and structure in anilato-based Single Ion Magnets. 2nd Workshop 'Young Researchers in Chemistry', 19-20 May 2022, Valencia, Spain, Poster at International Congress.

M. Capella-Argente; M. Gómez-Benmansour; C. Pintado-Zaldo; Samia Benmansour; C. J. Gómez-García From ladder to dimer, the size matters and from paramagnetic to single-ion magnets, lanthanoids make the difference. 2nd Workshop 'Young Researchers in Chemistry', 19-20 May 2022, Valencia, Spain, Poster at International Congress.

Carlos J. Gómez-García Coordination chemistry of anilato-type ligands with transition metals and lanthanoids: from tunable Tc to SMM. II Congreso Internacional de Química del Ecuador: 'Química para la vida y la sociedad', 30 May-3 June 2022, Chimborazo, Ecuador, Invited Speaker at the International Congress.

Noelia Maldonado; Ana Latorre; Félix Zamora; Álvaro Somoza; Carlos J. Gómez-García; Agatha Bastida; Pilar Amo-Ochoa A nanostructured Cu(II) coordination polymer based on alanine as a trifunctional mimic enzyme and efficient composite in the detection of Sphingobacteria. XXXVIII REUNIÓN BIENAL DE LA SOCIEDAD ESPAÑOLA DE QUÍMICA, 27-30 June 2022, Granada Spain, Conference in International Congress.

Carlos J. Gómez-García; Antonio Hernández-Paredes; Cristina Pintado-Zaldo; Javier Martínez-Ponce; Antonio Valero-Martínez; Miriam Gómez-Benmansour; Murta Capella- Argente; Samia Benmansour Slow relaxation of the magnetization in anilato-based coordination polymers. 8th European Conference on Molecular Magnetism, 4-7 July 2022, Rennes, France, Invited Speaker at the International Congress.

Antonio Hernández-Paredes; Samia Benmansour; María Bayona-Andrés; Gustavo López-Martínez; Carlos J. Gómez-García Reversible solvent exchange in luminescent anilato-based 2D lattices with slow relaxation of the magnetization. 8th European Conference on Molecular Magnetism, 4-7 July 2022, Rennes, France, Poster at International Congress.

Samia Benmansour; Cristina Pintado-Zaldo; Antonio Valero-Martínez; Javier Martínez- Ponce; Antonio Hernández-Paredes; Miriam Gómez-Benmansour; Carlos J. Gómez-García The influence of ethylene glycol versatility on magnetic properties and structure in anilato-based Single Ion Magnets. 8th European Conference on Molecular Magnetism, 4-7 July 2022, Rennes, France, Poster at International Congress.

Amani Hind Benahsene; Fatiha Guenifa; Raounek Rouag; Carlos J. Gómez García; Lamia Bendjeddou Synthesis, characterization, crystal structure, hirshfeld surface analysis and magnetic properties of the first dapson molecule copper coordination complex. National Seminar of Physics, Chemistry and their Applications (NSPCA'23), 6-7 March 2023, Bordj-Bou-Arreridj, Algeria, Poster at International Congress.

Carlos J. Gómez-García; Samia Benmansour; Antonio Hernández-Paredes; Cristian Martínez-Hernández; Cristina Pintado-Zaldo; Javier Martínez-Ponce; Antonio Valero-Martínez; Miriam Gómez-Benmansour Anilato-based layered ferrimagnets and single-ion magnets. 5th International Conference on Functional Molecular Materials. FUNMAT2023, 29-31 March 2023, Cracovia, Poland, Invited Speaker at the International Congress.

Amani Hind Benahsene; Fatiha Guenifa; Raounek Rouag, Carlos J. Gómez-García; Lamia Bendjeddou Synthesis, crystal structure, Hirshfeld surface analysis and magnetic properties of new copper coordination complex diaquabis(4,4'-diaminodimethylsulfone-k-N)-bis(N,N'-dimethylformamide-k-O) copper(II) dinitrate. 1er Séminaire National de Chimie Appliquée (SNCA23), Blida, Algeria, 9-10 May 2023, Poster at International Congress.

Sofía H. Casal-García; Samia Benmansour; Carlos J. Gómez-García A Dy^III Layered MOF with Field-Induced Slow Relaxation of the Magnetization. 3er Workshop for Young Researchers in Chemistry, 18-19 May 2023, Valencia, Spain, Conference in International Congress.

Carlos J. Gómez-García; Samia Benmansour; Antonio Hernández-Paredes; Cristian Martínez-Hernández; Cristina Pintado-Zaldo; Javier Martínez-Ponce; Antonio Valero-Martínez; Miriam Gómez-Benmansour The use of anilato ligands to construct magnetic and conducting MOFs XXXIX REUNIÓN BIENAL DE LA SOCIEDAD ESPAÑOLA DE QUÍMICA, 25-29 June 2023, Zaragoza, Spain, Invited Speaker at the International Congres.

Carlos J. Gómez-García; Samia Benmansour; Antonio Hernández-Paredes; Cristian Martínez-Hernández; María Bayona-Andrés Post-synthetic tunning of the magnetic properties in layered magnets and single-ion magnets (SIM). Emerging Research on Molecule-Based Magnets: from Theory to Experiment. 2023 Pre-ICMM Symposium, Guangzhou, China, 7-9 Septiembre 2023, Invited Speaker at the International Congress.

Carlos J. Gómez-García; Samia Benmansour; Antonio Hernández-Paredes; Cristina Pintado-Zaldo; Sofía H. Casal-García From 0D to 2D and 3D anilato-based single-molecule and single-ion magnets. 18th International Conference on Molecule-Based Magnets - ICMM2023, Nanjing, China, 10-14 Septiembre 2023, Conference in International Congress.

Carlos J. Gómez-García; Samia Benmansour; Cristian Martínez-Hernández Multifunctional molecule-based magnets with anilato ligands. Multifunctional Molecule-Based Materials. Post-ICMM 2023 Symposium, Tianjin, China,15-17 Septiembre 2023, Invited Speaker at the International Congress.

Cristina Pintado-Zaldo; Samia Benmansour; Carlos J. Gómez-García Single Ion Magnets based on anilato and ethylene glycol. 1st European School on Advanced Materials. ESAM, 15-18 Octubre 2023, Gandía, Spain, Conference in International Congress.

Sofia H. Casal-García; Samia Benmansour; Carlos J. Gómez-García A New two-Dimensional MOF with field induced Single Ion Magnet behaviour. 1st European School on Advanced Materials. ESAM, 15-18 Octubre 2023, Gandía, Spain, Conference in International Congress.

Carlos J. Gómez-García Conducting 2D and 3D MOFs. Measurements, mechanisms and types. 1st European School on Advanced Materials. ESAM, 15-18 Octubre 2023, Gandía, Spain, Invited Speaker at the International Congress.

Raounek Rouag; Amani Hind Benahsene; Lamia Bendjeddou; Carlos J. Gómez-García; Merazig Hocine Synthesis, characterization, crystal structure and magnetic properties of the first dapson molecule copper coordination complex. 1st International on Physica-Chemistry, Materials Science and Applied Mathematics (IPCSAM'23), 27-28 November 2023, Skikda, Algeria, Poster at International Congress.

Carlos J. Gómez-García, Samia Benmansour, Antonio Hernández-Paredes, Cristina Pintado-Zaldo, Sofía H. Casal-García, Javier Martínez-Ponce Magnetic and Conducting 2D and 3D Metal Organic Frameworks. International Conference on Natural Sciences and Engineering for Sustainable Development (NSESD2024), 6-7 Marzo 2024, Asansol, West Bengal, India, Invited Speaker at the International Congress.

Cristina Pintado-Zaldo, Louise Bureller, Javier Martínez-Ponce, Sofía H. Casal-García, Carlos J. Gómez-García, Samia Benmansour The first tris(anilato)metalate complex with a divalent cation and the first trimer with an anilato ligand. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.52, Conference in International Congress.

Carlos J. Gómez-García, Cristina Pintado-Zaldo, Javier Martínez-Ponce, Sofía H. CasalGarcía, Samia Benmansour Slow magnetic relaxation in layered lanthanoid-anilato lattices. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.132, Conference in International Congress.

Sofía H. Casal-García, Gonzalo de Joz Latorre, Cristina Pintado-Zaldo, Javier MartínezPonce, Carlos J. Gómez-García, Samia Benmansour Transition metal-based magnetic heteroleptic chains with anilato and imidazole-type ligands. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.150, Poster at International Congress.

Cristina Pintado-Zaldo, Louise Bureller, Javier Martínez-Ponce, Sofía H. Casal-García, Carlos J. Gómez-García, Samia Benmansour The first tris(anilato)metalate complex with a divalent cation and the first trimer with an anilato ligand. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.162, Poster at International Congress.

Samia Benmansour, Javier Martínez-Ponce, Marco Segura-Andreu, Cristina Pintado-Zaldo, Sofía H. Casal-García, Carlos J. Gómez-García Slow relaxation of the magnetization in lanthanoid dimers with an asymmetric anilato ligand. 9th European Conference on Molecular Magnetism, 14-19 July 2024, Krakow-Poland, P.186, Poster at International Congress.

Samia Benmansour, Carlos J. Gómez García, Antonio Hernandez Paredes Reversible solvents exchange in layered MOFs with slow relaxation of the magnetization. 3rd Asian Conference on Molecular Magnetism, 1 – 4 September 2024, Busan, Republic of Korea, Conference in International Congress.

Carlos J. Gómez García, Samia Benmansour, Cristian Martínez-Hernández Ferrimagnetic order in layered anilato-based heterometallic lattices. 3rd Asian Conference on Molecular Magnetism, 1 – 4 September 2024, Busan, Republic of Korea, Invited Speaker at the International Congress.

Ph.D. Thesis, Degree Thesis and Research Reports

Carmen Llopis Borrego Síntesis de redes extendidas de lantanoides y ligandos anilato en medio acuoso. Faculty of Chemistry, University of Valencia, Valencia, 2022, Bachelor's thesis.

Marco Segura Andreu Síntesis y caracterización de redes magnéticas porosas con lantanoides y ligandos de tipo anilato asimétricos. Faculty of Chemistry, University of Valencia, Valencia, 2022, Bachelor's thesis.

Cristina Pintado Zaldo Síntesis y caracterización de redes metal-orgánicas (MOF) con propiedades de imanes mono-moleculares (SMM). Faculty of Chemistry, University of Valencia, Valencia, 2022, Master's thesis.

Celso Iniesta Martín Desarrollo de nuevas estrategias para la idenficación y cuantificación de escopolamina en bebidas alcohólicas y no alcohólicas. Faculty of Chemistry, University of Valencia, Valencia, 2023, Bachelor's thesis.

Cristian Martínez Hernández Sensores magnéticos basados en polímeros de coordinación porosos con ordenamiento magnético. Faculty of Chemistry, University of Valencia, Valencia, 2023, Ph.D. thesis.

Antonio Hernández Paredes Redes metal-orgánicas magnéticas con relajación lenta de la magnetización basadas en ligandos anilatos. Faculty of Chemistry, University of Valencia, Valencia, 2024, Ph.D. thesis.

• MCiencia - Innovation