GIUV2023-546
As is well known, one of the main concerns of our society revolves around finding ways to continue our current lifestyle while establishing a green economy, in which energy, raw materials and value-added products are produced taking into account the principles of sustainability. In this direction, research into new materials that can be used as catalysts in fine chemistry and field of energy has much to contribute to the development of sustainable processes. In this sense, our research focuses on the design of materials that can serve as catalysts for organic reactions relevant to the synthesis of compounds of interest, such as drugs, pigments, agrochemicals, etc. In our research, both the development aspects of sustainable synthetic methodologies, taking into account the use of accessible and low toxic reagents (carbon dioxide, urea, diols, hydrogen, etc.) as far as posible, as well as the design aspects of the catalyst will be key. Regarding the latter aspect, in this group, we intend to design and characterize stable and reusable materials whose structure adapts to the needs of the reaction to be catalysed. Our interest so far has focused on the design of nanomaterials based on...As is well known, one of the main concerns of our society revolves around finding ways to continue our current lifestyle while establishing a green economy, in which energy, raw materials and value-added products are produced taking into account the principles of sustainability. In this direction, research into new materials that can be used as catalysts in fine chemistry and field of energy has much to contribute to the development of sustainable processes. In this sense, our research focuses on the design of materials that can serve as catalysts for organic reactions relevant to the synthesis of compounds of interest, such as drugs, pigments, agrochemicals, etc. In our research, both the development aspects of sustainable synthetic methodologies, taking into account the use of accessible and low toxic reagents (carbon dioxide, urea, diols, hydrogen, etc.) as far as posible, as well as the design aspects of the catalyst will be key. Regarding the latter aspect, in this group, we intend to design and characterize stable and reusable materials whose structure adapts to the needs of the reaction to be catalysed. Our interest so far has focused on the design of nanomaterials based on a metal oxide- or graphene-type support on which nanoparticles, clusters or metal complexes have been deposited. These materials have been applied as catalysts mainly in hydrogenation, hydrogen transfer and carbonylation reactions.
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- Sintesis y caracterizacion de nuevos materiales basados en nanoparticulas o clusteres metalicos sobre diferentes matrices con actividad catalitica
- Desarrollo de procesos cataliticos para reacciones de hidrogenacion o funcionalizacion hidrogenativa de derivados de acido carboxilico
- Desarrollo de procesos cataliticos para reacciones de carbonilacion o carboxilacion
- Desarrollo de procesos cataliticos de tipo transferencia de hidrogeno para la obtencion de compuestos organicos de interes
- Desarrollo de sistemas cataliticos para reacciones de valorizacion de dioxido de carbono y para sistemas de tipo Liquid Organic Hydrogen Carrier
- Design of materials as catalysts for hydrogenation.In this line of research we aim to design materials with the appropriate structure to carry out the activation of hydrogen and the substrate to be hydrogenated, usually a carboxylic acid derivative.
- Design of materials as catalysts for hydrogen transfer.In this line of research we aim to design materials with the appropriate structure to carry out the dehydrogenative activation of alcohol or amine substrates for hydrogen self-transfer reactions or dehydrogenative coupling.
- Design of materials as catalysts for activation of CO and carbon dioxide.In this line of research we aim to design materials with the appropriate structure to carry out the activation of CO and carbon dioxide in the context of obtaining complex organic molecules.
| Name | Nature of participation | Entity | Description |
|---|---|---|---|
| ROSA ADAM ORTIZ | Director | Universitat de València |
- -
- Hidrogenación; catálisis heterogénea; derivados de ácido carboxílico
- Transferencia de hidrógeno; dioles; aminas; ureas; heterociclos
- Dióxido de carbono; monóxido de carbono
